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An antibiotic composite electrode for improving the sensitivity of electrochemically active biofilm biosensor

《环境科学与工程前沿（英文）》 2022年 第16卷 第8期 doi: 10.1007/s11783-022-1518-7

摘要：

• Antibiotic azithromycin employed in graphite electrode for EAB biosensor.

关键词： AZM@GP composite electrode     EAB-biosensor     Water quality early-warning    

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NiCo2O4@quinone-rich N–C core–shell nanowires as composite electrode for electric double layer capacitor

《化学科学与工程前沿（英文）》 2023年 第17卷 第4期   页码 373-386 doi: 10.1007/s11705-022-2223-6

摘要： The bind-free carbon cloth-supported electrodes hold the promises for high-performance electrochemical capacitors with high specific capacitance and good cyclic stability. Considering the close connection between their performance and the amount of carbon material loaded on the electrodes, in this work, NiCo2O4 nanowires were firstly grown on the substrate of active carbon cloth to provide the necessary surface area in the longitudinal direction. Then, the quinone-rich nitrogen-doped carbon shell structure was formed around NiCo2O4 nanowires, and the obtained composite was used as electrode for electric double layer capacitor. The results showed that the composite electrode displayed an area-specific capacitance of 1794 mF∙cm–2 at the current density of 1 mA∙cm–2. The assembled symmetric electric double layer capacitor achieved a high energy density of 6.55 mW∙h∙cm–3 at a power density of 180 mW∙cm–3. The assembled symmetric capacitor exhibited a capacitance retention of 88.96% after 10000 charge/discharge cycles at the current density of 20 mA∙cm–2. These results indicated the potentials in the preparation of the carbon electrode materials with high energy density and good cycling stability.

关键词： carbon cloth     NiCo2O4 nanowires     core−shell structure     quinone-rich     electric double layer capacitor    

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Presentation of regression analysis, GP and GMDH models to predict the pedestrian density in various

Iraj BARGEGOL; Seyed Mohsen HOSSEINIAN; Vahid NAJAFI MOGHADDAM GILANI; Mohammad NIKOOKAR; Alireza OROUEI

《结构与土木工程前沿（英文）》 2022年 第16卷 第2期   页码 250-265 doi: 10.1007/s11709-021-0785-x

摘要： In this study, the relationship between space mean speed (SMS), flow rate and density of pedestrians was investigated in different pedestrian facilities, including 1 walkway, 2 sidewalks, 2 signalized crosswalks and 2 mid-block crosswalks. First, statistical analysis was performed to investigate the normality of data and correlation of variables. Regression analysis was then applied to determine the relationship between SMS, flow rate, and density of pedestrians. Finally, two prediction models of density were obtained using genetic programming (GP) and group method of data handling (GMDH) models, and k-fold and holdout cross-validation methods were used to evaluate the models. By the use of regression analysis, the mathematical relationships between variables in all facilities were calculated and plotted, and the best relationships were observed in flow rate-density diagrams. Results also indicated that GP had a higher R2 than GMDH in the prediction of pedestrian density in terms of flow rate and SMS, suggesting that GP was better able to model SMS and pedestrian density. Moreover, the application of k-fold cross-validation method in the models led to better performances compared to the holdout cross-validation method, which shows that the prediction models using k-fold were more reliable. Finally, density relationships in all facilities were obtained in terms of SMS and flow rate.

关键词： pedestrian density     regression analysis     GP model     GMDH model    

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Comparative analysis of ceramic-carbonate nanocomposite fuel cells using composite GDC/NLC electrolyte

Muhammad I. Asghar, Sakari Lepikko, Janne Patakangas, Janne Halme, Peter D. Lund

《化学科学与工程前沿（英文）》 2018年 第12卷 第1期   页码 162-173 doi: 10.1007/s11705-017-1642-2

摘要： A comparative analysis of perovskite structured cathode materials, La Sr MnO (LSM), La Sr CoO (LSC), La Sr FeO (LSF) and La Sr Co Fe O (LSCF), was performed for a ceramic-carbonate nanocomposite fuel cell using composite electrolyte consisting of Gd Ce O (GDC) and a eutectic mixture of Na CO and Li CO . The compatibility of these nanocomposite electrode powder materials was investigated under air, CO and air/CO atmospheres at 550 °C. Microscopy measurements together with energy dispersive X-ray spectroscopy (EDS) elementary analysis revealed few spots with higher counts of manganese relative to lanthanum and strontium under pure CO atmosphere. Furthermore, electrochemical impedance (EIS) analysis showed that LSC had the lowest resistance to oxygen reduction reaction (ORR) (14.12 Ω·cm ) followed by LSF (15.23 Ω·cm ), LSCF (19.38 Ω·cm ) and LSM (>300 Ω·cm ). In addition, low frequency EIS measurements (down to 50 µHz) revealed two additional semi-circles at frequencies around 1 Hz. These semicircles can yield additional information about electrochemical reactions in the device. Finally, a fuel cell was fabricated using GDC/NLC nanocomposite electrolyte and its composite with NiO and LSCF as anode and cathode, respectively. The cell produced an excellent power density of 1.06 W/cm at 550 °C under fuel cell conditions.

关键词： electrode     fuel cell     low-temperature     nanocomposite     perovskite    

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Application of electrode materials and catalysts in electrocatalytic treatment of dye wastewater

《化学科学与工程前沿（英文）》 2021年 第15卷 第6期   页码 1427-1443 doi: 10.1007/s11705-021-2108-0

摘要： The dye industry produces a large amount of hazardous wastewater every day worldwide, which brings potential threaten to the global environment. As an excellent method for removal of water chroma and chemical oxygen demand, electrocatalytic methods are currently widely used in the treatment of dye wastewater. The selection and preparation of electrode materials and electrocatalysts play an important role on the electrocatalytic treatment. The aim of this paper is to introduce the most excellent high-efficiency electrode materials and electrocatalysts in the field of dye wastewater treatment. Many electrode materials such as metal electrode materials, boron-doped diamond anode materials and three-dimensional electrode are introduced in detail. Besides, the mechanism of electrocatalytic oxidation is summarized. The composite treatment of active electrode and electrocatalyst are extensively examined. Finally, the progress of photo-assisted electrocatalytic methods of dye wastewater and the catalysts are described.

关键词： electrocatalytic oxidation     electrode     electrocatalysis     dye wastewater    

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Quality control based on electrode displacement and force in resistance spot welding

Chuntao JI, Lipeng DENG

《机械工程前沿（英文）》 2010年 第5卷 第4期   页码 412-417 doi: 10.1007/s11465-010-0114-x

摘要： The behaviors of electrode displacement and force during spot welding under various conditions, such as different weld currents, electrode forces, and welding times, were studied. Tests were conducted on a 170?kVA MFDC spot welder. Data were collected via a multichannel high-speed data acquisition system and were analyzed with MATLAB. Behaviors of 5182 aluminum and mild steel in spot welding were compared. Results show that nugget expansion rate does not reach zero for aluminium as it does for mild steel as nugget grew to a certain size. A linear relationship is found between the nugget size and maximum expansion that facilitates online weld quality evaluation. An electrode force peak is observed and believed relevant to the sufficient nugget size.

关键词： aluminum     electrode displacement     electrode force     nugget size     data acquisition    

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A novel flow electrode capacitive deionization device with spindle-shaped desalting chamber

《环境科学与工程前沿（英文）》 2023年 第18卷 第4期 doi: 10.1007/s11783-024-1800-y

摘要：

● A spindle-shaped influent chamber was designed and equipped in FCDI system.

关键词： Spindle-shaped chamber     Desalination performance     Flow electrode capacitive deionization    

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Expression of heat shock protein gp96 in osteosarcoma and its clinical significance

GUO Weichun, CHEN Anmin

《医学前沿（英文）》 2008年 第2卷 第2期   页码 200-203 doi: 10.1007/s11684-008-0038-6

摘要： This study aims to detect the expression of heat shock protein gp96 (HSPgp96) in osteosarcoma and explore its role in anti-tumor immunity. Expression of HSPgp96 in 45 cases of osteosarcoma, including 24 cases of the osteoblast type, 21 cases of chondroblast type and 5 cases of normal bone tissue were detected by immunohistochemistry (IHC). The expression rate of HSPgp96 was 100% (45/45) in osteosarcoma, compared with 20% (1/5) in normal bone tissue. The average positive cell rates were 97.23% and 0.48% in osteosarcoma and normal bone tissue, respectively, and the difference between them was significant ( < 0.01). The positive cell rates in osteoblast type and chondroblast type were 97.78% and 96.56%, respectively, and the difference had no statistical significance ( > 0.05). The expression degree of HSPgp96 in osteosarcoma had a clear correlation with the pathologic degree ( < 0.05), while it had no relationship with the clinical stage ( > 0.05). The expression of HSPgp96 is high in osteosarcoma and it may be a significant index for judgment of malignancy degree and an important target site of anti-tumor immunity.
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A comprehensive assessment on the durability of gas diffusion electrode materials in PEM fuel cell stack

Arunkumar JAYAKUMAR

《能源前沿（英文）》 2019年 第13卷 第2期   页码 325-338 doi: 10.1007/s11708-019-0618-y

摘要： Polymer electrolyte membrane (PEM) fuel cell is the most promising among the various types of fuel cells. Though it has found its applications in numerous fields, the cost and durability are key barriers impeding the commercialization of PEM fuel cell stack. The crucial and expensive component involved in it is the gas diffusion electrode (GDE) and its degradation, which limits the performance and life of the fuel cell stack. A critical analysis and comprehensive understanding of the structural and functional properties of various materials involved in the GDE can help us to address the related durability and cost issues. This paper reviews the key GDE components, and in specific, the root causes influencing the durability. It also envisages the role of novel materials and provides a critical recommendation to improve the GDE durability.

关键词： PEM fuel cell     gas diffusion electrode(GDE)     gas diffusion layer(GDL)     membrane electrode assembly     durability     fuel cell catalyst    

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Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1065-1074 doi: 10.1007/s11705-023-2313-0

摘要： Lignocellulosic biomass such as plants and agricultural waste are ideal to tackle the current energy crisis and energy-related environmental issues. Carbon-rich lignin is abundant in lignocellulosic biomass, whose high-value transformation and utilization has been the most urgent problem to be solved. Herein, we propose a method for the preparation of porous carbon from lignin employing an H3PO4-assisted hydrothermal method. We characterize the as-prepared lignin-derived porous carbon and investigate its potential for energy storage. After assisted hydrothermal treatment followed by carbonization at 800 °C, the lignin-derived porous carbon displays a high specific capacitance (223.6 F·g–1 at 0.1 A·g–1) and excellent cycling ability with good capacitance retention. In this present study, the resultant lignin-derived porous carbon was used as the electrode of a supercapacitor, illustrating yet another potential high-value use for lignin, namely as a candidate for the sustainable fabrication of main supercapacitor components.

关键词： lignin     porous carbon     electrode     supercapacitor    

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Characterization of electrode fouling during electrochemical oxidation of phenolic pollutant

Xuefeng Liu, Shijie You, Fang Ma, Hao Zhou

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1345-7

摘要： Abstract • Electrode fouling is characterized by non-destructive characterization. • Electrode fouling is highly dependent on electrochemical process. • Active chlorine can prevent the formation of polymeric fouling film. Electrode fouling is a problem that commonly occurs during electro-oxidation water purification. This study focused on identifying the fouling behavior of Pt electrode associated with the formation of polymeric layer during electro-oxidation of phenol. The in situ electrochemical measurements and non-destructive observation of the electrode morphology were reported. The results demonstrated that the electrode fouling was highly dependent on thermodynamic process of electrode that was controlled by anode potential. At anode potential lower than 1.0 V vs SHE, the direct electro-oxidation caused the electrode fouling by the formation of polymeric film. The fouling layer decreased the electrochemically active surface area from 8.38 cm2 to 1.57 cm2, indicated by the formation of polymeric film with thickness of 2.3 mm, increase in mass growing at a rate of 3.26 μg/cm2/min. The degree to which the anode was fouled was independent of anion in the electrolyte. In comparison, at anode potential higher than 2.7 V vs SHE, the anions (e.g., chloride) could exert a major influence to the behavior of electrode fouling. The presence of chloride was shown to mitigate the fouling of electrode significantly through preventing the formation of polymeric film by active chlorine (e.g., Cl• and Cl2) produced from anodic oxidation of chloride. Since chloride is the most abundant anionic species existing in both natural and engineered water system, this study not only offers a deep insight into the mechanism of electrode fouling, but also suggests strategies for anti-fouling in the presence of chloride in electro-oxidation process.

关键词： Electro-oxidation     Electrode fouling     Polymeric film     Chloride ions    

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Electroreduction of hexavalent chromium using a porous titanium flow-through electrode and intelligent

《环境科学与工程前沿（英文）》 2023年 第17卷 第8期 doi: 10.1007/s11783-023-1697-x

摘要：

● Titanium-based flow-through electrode achieved high Cr(VI) reduction efficiency.

关键词： Flow-through electrode     Hexavalent chromium     Heavy metals     Neural network     Artificial intelligence    

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Latest development of double perovskite electrode materials for solid oxide fuel cells: a review

Shammya AFROZE, AfizulHakem KARIM, Quentin CHEOK, Sten ERIKSSON, Abul K. AZAD

《能源前沿（英文）》 2019年 第13卷 第4期   页码 770-797 doi: 10.1007/s11708-019-0651-x

摘要： Recently, the development and fabrication of electrode component of the solid oxide fuel cell (SOFC) have gained a significant importance, especially after the advent of electrode supported SOFCs. The function of the electrode involves the facilitation of fuel gas diffusion, oxidation of the fuel, transport of electrons, and transport of the byproduct of the electrochemical reaction. Impressive progress has been made in the development of alternative electrode materials with mixed conducting properties and a few of the other composite cermets. During the operation of a SOFC, it is necessary to avoid carburization and sulfidation problems. The present review focuses on the various aspects pertaining to a potential electrode material, the double perovskite, as an anode and cathode in the SOFC. More than 150 SOFCs electrode compositions which had been investigated in the literature have been analyzed. An evaluation has been performed in terms of phase, structure, diffraction pattern, electrical conductivity, and power density. Various methods adopted to determine the quality of electrode component have been provided in detail. This review comprises the literature values to suggest possible direction for future research.

关键词： double perovskites     electrode materials     hydrocarbon fuel     solid oxide fuel cells    

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Anti-β glycoprotein I antibodies in complex with β2 glycoprotein I induce platelet activation via two receptors: apolipoprotein E receptor 2' and glycoprotein I bα

null

《医学前沿（英文）》 2016年 第10卷 第1期   页码 76-84 doi: 10.1007/s11684-015-0426-7

摘要：

Anti-β2 glycoprotein I (anti-β2GP I ) antibodies are important contributors to thrombosis, especially in patients with antiphospholipid syndrome (APS). However, the mechanism by which anti-β2GP I antibodies are involved in the pathogenesis of thrombosis is not fully understood. In this report, we investigated the role of anti-β2GP I antibodies in complexes with β2GP I as mediators of platelet activation, which can serve as a potential source contributing to thrombosis. We examined the involvement of the apolipoprotein E receptor 2' (apoER2') and glycoprotein I ba (GP I bα) in platelet activation induced by the anti-β2GP I /β2GP I complex. The interaction between the anti-β2GP I /β2GP I complex and platelets was examined using in vitro methods, in which the Fc portion of the antibody was immobilized using protein A coated onto a microtiter plate. Platelet activation was assessed by measuring GP II b/ III a activation and P-selectin expression and thromboxane B2 production as well as p38 mitogen-activated protein kinase phosphorylation. Our results revealed that the anti-β2GP I /β2GP I complex was able to activate platelets, and this activation was inhibited by either the anti-GP I bα antibody or the apoER2' inhibitor. Results showed that the anti-β2GP I /β2GP I complex induced platelet activation via GP I bα and apoER2', which may then contribute to the prothrombotic tendency in APS patients.

关键词： anti-β2GP I /β2GP I complex     platelet     GP I bα     apoER2'     thrombosis    

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Enhanced electrochemical performance of CoNiS@TiCT electrode material through doping of cobalt element

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1440-1449 doi: 10.1007/s11705-023-2333-9

摘要： The composite electrode of CoNiSx and Ti3C2Tx MXene was successfully prepared using a one-step hydrothermal method under the in-situ doping of the cobalt element. The effects of in-situ doping of the cobalt element on the micromorphology and electrochemical performance of the electrodes were investigated. After in-situ doping of the cobalt element, NiS with a needle-like structure was converted into a CoNiSx with petal-like structure. The petal-like CoNiSx with a rough surface was very dense and evenly wrapped on the surface and interlamination of Ti3C2Tx, which helped increase the specific surface area and pore volume of the electrode. Under the identical test conditions, CoNiSx@Ti3C2Tx had a higher specific capacitance and capacitance retention than NiS@Ti3C2Tx. This result indicated that the in-situ doping of the cobalt element promoted the electrochemical performance of the electrode. The energy density of the CoNiSx@Ti3C2Tx/nickel foam (NF)//activated carbon (AC)/NF asymmetric supercapacitor device was 59.20 Wh·kg–1 at a power density of 826.73 W·kg–1, which was much higher than that of NiS@Ti3C2Tx/NF//AC/NF. Three CoNiSx@Ti3C2Tx/NF//AC/NF in series were able to illuminate the light emitting diode lamp for about 10 min, which was higher than the 5 min of three NiS@Ti3C2Tx/NF//AC/NF in series under the same condition. The CoNiSx@Ti3C2Tx/NF//AC/NF with high energy density had better application potential in energy storage than the NiS@Ti3C2Tx/NF//AC/NF.

关键词： MXene     supercapacitor     cobalt doping     structure characterization     electrochemical performance    

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标题 作者 时间 类型 操作

An antibiotic composite electrode for improving the sensitivity of electrochemically active biofilm biosensor

期刊论文

NiCo2O4@quinone-rich N–C core–shell nanowires as composite electrode for electric double layer capacitor

期刊论文

Presentation of regression analysis, GP and GMDH models to predict the pedestrian density in various

Iraj BARGEGOL; Seyed Mohsen HOSSEINIAN; Vahid NAJAFI MOGHADDAM GILANI; Mohammad NIKOOKAR; Alireza OROUEI

期刊论文

Comparative analysis of ceramic-carbonate nanocomposite fuel cells using composite GDC/NLC electrolyte

Muhammad I. Asghar, Sakari Lepikko, Janne Patakangas, Janne Halme, Peter D. Lund

期刊论文

Application of electrode materials and catalysts in electrocatalytic treatment of dye wastewater

期刊论文

Quality control based on electrode displacement and force in resistance spot welding

Chuntao JI, Lipeng DENG

期刊论文

A novel flow electrode capacitive deionization device with spindle-shaped desalting chamber

期刊论文

Expression of heat shock protein gp96 in osteosarcoma and its clinical significance

GUO Weichun, CHEN Anmin

期刊论文

A comprehensive assessment on the durability of gas diffusion electrode materials in PEM fuel cell stack

Arunkumar JAYAKUMAR

期刊论文

Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

期刊论文

Characterization of electrode fouling during electrochemical oxidation of phenolic pollutant

Xuefeng Liu, Shijie You, Fang Ma, Hao Zhou

期刊论文

Electroreduction of hexavalent chromium using a porous titanium flow-through electrode and intelligent

期刊论文

Latest development of double perovskite electrode materials for solid oxide fuel cells: a review

Shammya AFROZE, AfizulHakem KARIM, Quentin CHEOK, Sten ERIKSSON, Abul K. AZAD

期刊论文

Anti-β glycoprotein I antibodies in complex with β2 glycoprotein I induce platelet activation via two receptors: apolipoprotein E receptor 2' and glycoprotein I bα

null

期刊论文

Enhanced electrochemical performance of CoNiS@TiCT electrode material through doping of cobalt element

期刊论文